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By Charles L. Dodgson

ISBN-10: 141817985X

ISBN-13: 9781418179854

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7a) with a potential energy operator W z (R) while 'Pmf is an eigenfunction of another Schrodinger equation with a potential Wm(R). In quantum-mechanical calculations of transition probabilities we usually deal with a sin g 1 e set of orthonormal eigenfunctions. t the basis of the usual spectroscopic selection rules. These selection rules are formulated as "absolute"statements ("the line is there or it isn't") and therefore are also sometimes called exclusion rules. 5) All other transitions are forbidden in the dipole approximation.

But when N increases, the number of normal modes with which the electronic transition of the impurity center can interact also increases, and therefore it is not correct to set qso equal to zero. dq. dq. 8) The first term on the right-hand side is unity because the vibrational functions are normalized. The second term is zero since differentiating a harmonic oscillator wave function changes its parity and one gets an integral of an odd function between symmetric limits. 9) It is necessary to comment on the meaning of the mass ms.

8) The first term on the right-hand side is unity because the vibrational functions are normalized. The second term is zero since differentiating a harmonic oscillator wave function changes its parity and one gets an integral of an odd function between symmetric limits. 9) It is necessary to comment on the meaning of the mass ms. Since we speak of normal modes, the numerical value of m s, strictly speaking, is not generally defined. One speaks of the frequency of the normal mode. The force constant and the mass are not separately defined, as can easily be seen from Appendix II.

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An elementary treatise on determinants by Charles L. Dodgson


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